November 3, 2020 -- A team of European researchers discovered a new high-pressure mineral in the lunar meteorite Oued Awlitis 001, named donwilhelmsite [CaAl4Si2O11]. The team around Jörg Fritz from the Zentrum für Rieskrater und Impaktforschung Nördlingen, Germany and colleagues at the German Research Centre for Geoscience GFZ in Potsdam, Museum für Naturkunde Berlin, Natural History Museum Vienna, Institute of Physics of the Czech Academy of Science, Natural History Museum Oslo, University of Manchester, and Deutsches Zentrum für Luft und Raumfahrt Berlin published their findings in the scientific journal “American Mineralogist”.
Besides the about 382 kilograms of rocks
and soils collected by the Apollo and Luna missions, lunar meteorites allow
valuable insights into the formation of the Moon. They are ejected by impacts
onto the lunar surface and subsequently delivered to Earth.
Some of these meteorites experienced
particularly high temperatures and pressures. The extreme physical conditions
often led to shock melting of microscopic areas within these meteorites. These
shocked areas are of great relevance as they mirror pressure and temperature
regimes similar to those prevailing in the Earth’s mantle. Therefore, the
microscopic shock melt areas are natural crucibles hosting minerals that are
otherwise naturally inaccessible at the Earth’s surface. Minerals like
wadsleyite, ringwoodite, and bridgmanite, constitute large parts of the Earth’s
mantle. Theses crystals were synthesized in high-pressure laboratory
experiments. As natural minerals they were first described and named based on
their occurrences in meteorites.
The new mineral donwilhelmsite is the
first high-pressure mineral found in meteorites with application for subducted
terrestrial sediments. It is mainly composed of calcium, aluminum, silicon, and
oxygen atoms. Donwilhelmsite was discovered within shock melt zones of the
lunar meteorite Oued Awlitis 001 found in 2014 in the Western Sahara. This
meteorite is compositionally similar to rocks comprising the Earth’s
continents. Eroded sediments from these continents are transported by wind and
rivers to the oceans, and subducted into the Earth’s mantle as part of the
dense oceanic crust. While being dragged deeper into the Earth mantle the
pressure and temperature increases, and the minerals transform into denser
mineral phases. The newly discovered mineral donwilhelmsite forms in 460 to 700
kilometre depth. In the terrestrial rock cycle, donwilhelmsite is therefore an
important agent for transporting crustal sediments through the transition zone
separating the upper and lower Earth’s mantle.
This pan-European collaboration was
essential to obtain the lunar meteorite, recognize the new mineral, understand
its scientific relevance, and to determine the crystal structure of the tiny,
the thousands part of a millimeter thick, mineral crystal with high accuracy.
"At the GFZ, we used transmission electron microscopy to investigate
microstructural aspects of the samples," says Richard Wirth from the
section "Interface Geochemistry". "Our investigations and the
crystal structure analyses of the colleagues from the Czech Republic once again
underline the importance of transmission electron microscopy in the geosciences".
The new mineral was named in honor of
the lunar geologist Don E. Wilhelms, an American scientist involved in landing
site selection and data analyses of the Apollo space missions that brought to
Earth the first rock samples from the Moon. Part of the meteorite Oued Awlitis
001, acquired by crowdfunding initiative „Help us to get the Moon!”, is on
display at the Natural History Museum Vienna.
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