Scientists have found that lightning bolts and, surprisingly, subvisible discharges that cannot be seen by cameras or the naked eye produce extreme amounts of the hydroxyl radical and hydroperoxyl radical.
From:
Penn State
April 29, 2021 -- The hydroxyl radical
is important in the atmosphere because it initiates chemical reactions and
breaks down molecules like the greenhouse gas methane.
Lightning bolts break apart nitrogen and
oxygen molecules in the atmosphere and create reactive chemicals that affect
greenhouse gases. Now, a team of atmospheric chemists and lightning scientists
have found that lightning bolts and, surprisingly, subvisible discharges that
cannot be seen by cameras or the naked eye produce extreme amounts of the
hydroxyl radical -- OH -- and hydroperoxyl radical -- HO2.
The hydroxyl radical is important in the
atmosphere because it initiates chemical reactions and breaks down molecules
like the greenhouse gas methane. OH is the main driver of many compositional
changes in the atmosphere.
"Initially, we looked at these huge
OH and HO2 signals found in the clouds and asked, what is wrong
with our instrument?" said William H. Brune, distinguished professor of
meteorology at Penn State. "We assumed there was noise in the instrument,
so we removed the huge signals from the dataset and shelved them for later
study."
The data was from an instrument on a
plane flown above Colorado and Oklahoma in 2012 looking at the chemical changes
that thunderstorms and lightning make to the atmosphere.
But a few years ago, Brune took the data
off the shelf, saw that the signals were really hydroxyl and hydroperoxyl, and
then worked with a graduate student and research associate to see if these
signals could be produced by sparks and subvisible discharges in the
laboratory. Then they did a reanalysis of the thunderstrom and lightning
dataset.
"With the help of a great
undergraduate intern," said Brune, "we were able to link the huge
signals seen by our instrument flying through the thunderstorm clouds to the
lightning measurements made from the ground."
The researchers report their results
online today (April 29) in Science First Release and the Journal
of Geophysical Research -- Atmospheres.
Brune notes that airplanes avoid flying
through the rapidly rising cores of thunderstorms because it is dangerous, but
can sample the anvil, the top portion of the cloud that spreads outward in the
direction of the wind. Visible lightning happens in the part of the anvil near
the thunderstorm core.
"Through history, people were only
interested in lightning bolts because of what they could do on the
ground," said Brune. "Now there is increasing interest in the weaker
electrical discharges in thunderstorms that lead to lightning bolts."
Most lightning never strikes the ground,
and the lightning that stays in the clouds is particularly important for affecting
ozone, and important greenhouse gas, in the upper atmosphere. It was known that
lightning can split water to form hydroxyl and hydroperoxyl, but this process
had never been observed before in thunderstorms.
What confused Brune's team initially was
that their instrument recorded high levels of hydroxyl and hydroperoxyl in
areas of the cloud where there was no lightning visible from the aircraft or
the ground. Experiments in the lab showed that weak electrical current, much
less energetic than that of visible lightning, could produce these same
components.
While the researchers found hydroxyl and
hydroperoxyl in areas with subvisible lightning, they found little evidence of
ozone and no evidence of nitric oxide, which requires visible lightning to
form. If subvisible lightning occurs routinely, then the hydroxyl and
hydroperoxyl these electrical events create need to be included in atmospheric
models. Currently, they are not.
According to the researchers,
"Lightning-generated OH (hydroxyl) in all storms happening globally can be
responsible for a highly uncertain but substantial 2% to 16% of global
atmospheric OH oxidation."
"These results are highly
uncertain, partly because we do not know how these measurements apply to the
rest of the globe," said Brune. "We only flew over Colorado and
Oklahoma. Most thunderstorms are in the tropics. The whole structure of high
plains storms is different than those in the tropics. Clearly we need more
aircraft measurements to reduce this uncertainty."
Other researchers at Penn State include
Patrick J. McFarland, undergraduate; David O. Miller, doctoral recipient; and
Jena M. Jenkins, doctoral candidate, all in meteorology and atmospheric
science.
No comments:
Post a Comment